Alabama CDL HazMat study materials
Alabama CDL HazMat study resources

Alabama CDL HazMat cheat sheet

Alabama CDL HazMat · Keep the key ideas within reach.

Quick reference

HazMat Regulations, Definitions, and Communication Rules

  • Hazardous material means a substance or material the Secretary of Transportation determines capable of posing an unreasonable risk to health, safety, and property when transported in commerce.

  • HazMat employees must be trained in general awareness/familiarization, function-specific duties, safety, and security awareness; recurrent training is required at least every 3 years.

  • Shipping paper records must be retained for 2 years (hazardous waste manifests for 3 years) and made available to authorized persons.

  • The four communication elements are shipping papers, package marking, package labeling, and vehicle placarding.

  • A HazMat employer must certify each employee's training and provide a certificate with the employee's name, completion date, and a description of training.

  • Emergency response information must accompany every hazardous materials shipment and be immediately available during transport.

  • Carriers must report certain HazMat incidents to the National Response Center at 1-800-424-8802.

  • Registration with PHMSA is required for carriers of high-hazard materials such as large quantities of certain explosives and poisons.

Quick reference

Shipping Papers

  • Basic description order: proper shipping name, hazard class or division, UN/NA identification number, and packing group.

  • The UN/NA number may be placed before or after the basic description; when after, it follows the packing group.

  • Total quantity must be shown by unit of measurement (weight, volume, or number of pieces) and by hazard class.

  • The shipper's certification statement and emergency response telephone number must appear on the shipping paper.

  • When a shipping paper covers both hazardous and non-hazardous materials, HazMat entries must be distinguished (for example, by an X or the word HazMat).

  • Shipping papers must be within the driver's reach while driving, visible to a person entering the cab, and kept on top of or with other papers.

  • The proper shipping name must be the one shown in the Hazardous Materials Table, not a trade or brand name.

Quick reference

Marking, Labeling, and Placarding

  • A label is a 4-inch square diamond; a placard is a 10 3/4-inch square diamond on point.

  • Placards are required for 1,001 pounds or more aggregate gross weight of a hazard class in one vehicle, and for any quantity of Table 2 materials.

  • Table 1 materials require placarding regardless of quantity; Table 2 materials require placards only at 1,001 pounds or more.

  • DANGEROUS placard may be used for two or more Table 2 categories totaling 1,001 pounds or more when no single category reaches that amount.

  • The UN/NA identification number must appear on placards or as orange panels for bulk packages, and on both sides and both ends of tank vehicles.

  • Non-bulk packages require the proper shipping name and UN/NA number marked on the package, plus required labels.

  • Placards must be affixed on both sides and both ends of the vehicle, and must be removed or turned when no longer carrying the material.

  • Hazard class labels communicate the primary and subsidiary hazards; subsidiary labels are placed to the right of the primary label.

Quick reference

Loading, Unloading, and Segregation

  • Never load hazardous materials into a trailer containing food or animal feed unless they are adequately separated and protected.

  • Cyanides and acids must be kept apart; acid spills on cyanides can release deadly hydrogen cyanide gas.

  • Poisonous materials must not be loaded with or near foodstuffs or animal feed.

  • Explosives may not be loaded with detonators or other initiating devices in the same vehicle.

  • Chlorine and ammonia must not be carried together; mixing can produce a violent reaction.

  • Before loading, check for leaks, damaged packages, and improper labels or markings; refuse damaged packages.

  • Cargo must be secured against shifting; use blocking and bracing appropriate to the package type.

  • When loading or unloading explosives, turn off the engine, set the parking brake, and do not smoke or allow open flame.

Quick reference

Bulk Packages, Cargo Tanks, and Tank Vehicles

  • A bulk package holds more than 119 gallons for liquids, more than 882 pounds for solids, or more than 1,001 pounds water capacity for gases.

  • Cargo tanks must have internal or external valves that close automatically in case of fire, and must be marked with the UN/NA number and placards.

  • Before loading a cargo tank, verify that the tank is the correct type for the material and that it is clean and free of incompatible residue.

  • Tank vehicles must have at least one placard on each side and each end, plus the UN/NA number displayed.

  • The driver must ensure tank hatches are closed and secured before moving and that unloading lines are disconnected.

  • Cargo tank rollover protection and baffles help prevent surge and protect the tank in a crash.

  • Never smoke or use flame near cargo tanks; check for leaks around valves, hoses, and fittings before and after loading.

  • A tank vehicle carrying a Division 2.1 flammable gas or Division 2.3 poison gas requires special handling and placarding regardless of quantity.

Quick reference

Driving and Parking Rules for Hazardous Materials

  • Never park within 5 feet of a roadway, and never park a placarded vehicle within 300 feet of an open flame or bridge, tunnel, or other restricted area.

  • When parking a placarded vehicle, keep it attended, or if unattended, secure it and set the parking brake and chock the wheels.

  • Avoid tunnels, bridges, and heavily populated areas when routing a placarded load; follow designated routes.

  • Do not smoke or allow smoking within 25 feet of a placarded vehicle.

  • Use the engine brake and lower gears on downgrades; do not ride the brakes.

  • Stop before railroad crossings and check both directions; do not shift gears while crossing the tracks.

  • Reduce speed in curves and on wet or icy roads; hazardous loads have a higher center of gravity.

  • If a placarded vehicle is involved in a crash, stop, secure the scene, and notify authorities immediately.

Quick reference

Emergency Response, Incidents, and Reporting

  • Immediately report any spill, leak, fire, or accident involving hazardous materials to the National Response Center at 1-800-424-8802.

  • Use the Emergency Response Guidebook: identify the material by UN/NA number or name, then follow the guide number's initial actions.

  • The ERG guide pages give protective actions: isolation distances, protective clothing, and fire/ spill response.

  • Call for help from a safe distance and upwind; do not attempt to fight a fire involving explosives, gases, or unknown materials.

  • Keep people away and upwind; establish an isolation zone per the ERG guide number.

  • A written incident report and follow-up may be required; retain copies of shipping papers and incident records.

  • Do not move a leaking package unless necessary to prevent further damage; contain and absorb spills if trained and equipped.

  • After an incident, do not return to the vehicle until authorities declare it safe.

Quick reference

Hazard Classes, Divisions, and Hazard Identification

  • Class 1 explosives (divisions 1.1-1.6), Class 2 gases (2.1 flammable, 2.2 nonflammable, 2.3 toxic), Class 3 flammable liquids.

  • Class 4 flammable solids (4.1), spontaneously combustible (4.2), dangerous when wet (4.3); Class 5 oxidizers (5.1) and organic peroxides (5.2).

  • Class 6 toxic (6.1) and infectious substances (6.2); Class 7 radioactive; Class 8 corrosives; Class 9 miscellaneous.

  • Packing groups: I = great danger, II = moderate danger, III = minor danger.

  • A hazard class number identifies the primary hazard; subsidiary hazards are shown on labels and in the shipping description.

  • Division 2.3 toxic gas and Division 6.1 toxic materials require special handling and placarding regardless of quantity.

  • The UN/NA number and proper shipping name identify the specific material; the class number identifies the hazard type.

  • Class 7 radioactive materials require special routing, securement, and dose-rate limits.

Quick reference

Security Awareness and Safe Havens

  • Security awareness means recognizing and reporting suspicious behavior, tampering, or unusual inquiries about hazardous loads.

  • Do not discuss the contents of a hazardous load with unauthorized persons; share information only on a need-to-know basis.

  • Keep shipping papers and vehicle keys secure; lock the vehicle when unattended.

  • Report suspicious activity to the carrier and to local authorities; do not confront suspicious persons.

  • A safe haven is a pre-identified secure location where a driver can stop if concerned about security or safety.

  • Verify the identity of anyone requesting to inspect or take custody of a hazardous load.

  • Watch for signs of tampering with seals, valves, or placards, and report them before moving.

  • Plan routes and stops in advance; avoid unplanned stops in high-crime or isolated areas with hazardous loads.