Solid State Physics
Solid State Physics in GATE PH tests crystal structures, Miller indices, reciprocal lattices, Bragg diffraction, phonons, free-electron and band theory, semiconductors, magnetism, and superconductivity. Numerical questions frequently use a cubic crystal and a diffraction angle.
Core rules and concepts
- For a cubic lattice, the interplanar spacing is d_hkl = a/√(h² + k² + l²). Bragg's law is 2d sinθ = nλ.
- The reciprocal lattice vector is G = h b₁ + k b₂ + l b₃. Diffraction peaks occur when the scattering vector equals a reciprocal lattice vector.
- The Debye model gives a phonon heat capacity proportional to T³ at low temperature and approaching the Dulong-Petit value at high temperature.
- In band theory, the effective mass is m* = ħ²/(d²E/dk²). A negative curvature at a band maximum corresponds to a hole-like carrier.
- Semiconductors: carrier concentration depends on the density of states and the Fermi-Dirac distribution; doping shifts the Fermi level.
Worked example
A cubic crystal has lattice constant a = 4 Å. For first-order Bragg reflection from (100) planes, d = a = 4 Å. With λ = 1.54 Å, Bragg's law gives sinθ = λ/(2d) = 1.54/8 = 0.1925. Thus θ ≈ 11.1°. The corresponding diffraction angle 2θ is about 22.2°.
Traps that cost marks
- Using d = a for non-cubic or higher-index planes.
- Forgetting the factor 2 in Bragg's law or reporting θ instead of 2θ.
- Missing systematic absences caused by the basis, not the lattice.
- Confusing the reciprocal lattice factor 2π with the crystallographic convention.