Missouri CDL Hazmat study materials
Missouri CDL Hazmat study resources

Missouri CDL Hazmat key terms

Missouri CDL Hazmat · Get comfortable with the vocabulary.

Hazardous Materials Endorsement (H)

A letter added to a Missouri commercial driver license after the driver passes the hazmat knowledge test, a TSA security threat assessment, and any required background checks. It authorizes driving vehicles carrying placarded amounts of hazardous materials.

Related: Placard, Security Threat Assessment, Reportable Quantity
Hazard Class

One of nine numbered categories the DOT uses to group materials by their dominant risk, such as explosives, gases, flammables, oxidizers, toxics, and corrosives. The class number appears on shipping papers, package labels, and vehicle placards.

Related: Division, Placard, Shipping Paper
Division

A subdivision within a hazard class that narrows the risk, such as dividing flammable liquids by flash point or gases by toxicity and flammability. Divisions carry decimal numbers like 2.1, 4.3, or 6.1 on papers and placards.

Related: Hazard Class, Flash Point, Placard
Hazard Identification Number

A two- or three-digit code shown in the upper half of some international-style placards and on shipping papers. The first digit signals the primary hazard and later digits add information, such as 3 for flammable or 8 for corrosive.

Related: Placard, UN Identification Number, Shipping Paper
UN Identification Number

A four-digit number assigned to a specific hazardous material, such as UN1203 for gasoline. It appears on shipping papers, package markings, orange panels, and some placards so responders can identify the product quickly.

Related: Hazard Identification Number, Placard, Shipping Paper
Placard

A large diamond-shaped warning sign placed on the outside of a vehicle, bulk package, or freight container to show the hazard class of its contents. Placards warn the public and emergency responders before they approach.

Related: Hazard Class, Placarding Threshold, Hazardous Materials Endorsement (H)
Placarding Threshold

The quantity of a hazardous material that triggers a placard requirement, commonly 1,001 pounds aggregate gross weight for Table 2 materials in a transport vehicle. Table 1 materials require placards at any amount.

Related: Placard, Table 1 Material, Table 2 Material
Table 1 Material

A hazardous material listed in the placarding table that must be placarded in any quantity when offered for transport, such as certain poison gases and explosives. There is no small-quantity exception for these materials.

Related: Table 2 Material, Placarding Threshold, Placard
Table 2 Material

A hazardous material listed in the placarding table that requires placards only when the aggregate gross weight in the vehicle reaches 1,001 pounds or more. Most common fuels and many industrial chemicals fall in this table.

Related: Table 1 Material, Placarding Threshold, Aggregate Gross Weight
Aggregate Gross Weight

The combined weight of all packages of a hazardous material plus the weight of the packaging, used to decide whether Table 2 placards are required. The total is figured for the whole vehicle load, not per package.

Related: Table 2 Material, Placarding Threshold, Bulk Package
Bulk Package

A packaging with a capacity greater than 119 gallons for liquids, 882 pounds for solids, or 1,000 pounds of water capacity for gases. Bulk packages follow different placarding and marking rules than non-bulk packages.

Related: Non-Bulk Package, Aggregate Gross Weight, Cargo Tank
Non-Bulk Package

A package smaller than the bulk thresholds, such as drums, boxes, or cylinders under the capacity limits. Non-bulk packages usually carry hazard labels and markings rather than being individually placarded.

Related: Bulk Package, Hazard Warning Label, Package Marking
Hazard Warning Label

A small diamond-shaped sticker applied to a non-bulk package that shows its hazard class or division. Labels communicate the hazard to handlers, but they do not replace vehicle placards or shipping paper entries.

Related: Non-Bulk Package, Placard, Package Marking
Shipping Paper

The documentation that travels with a hazardous materials shipment and describes the material, hazard class, UN number, quantity, and shipper. Drivers must keep it within reach, readily visible, and available to emergency responders.

Related: Basic Description, Emergency Response Information, UN Identification Number
Basic Description

The required sequence on a shipping paper: proper shipping name, hazard class or division, UN identification number, and packing group, in that order. The order lets responders read the key facts quickly at an incident scene.

Related: Shipping Paper, Packing Group, Proper Shipping Name
Proper Shipping Name

The official name for a hazardous material as listed in the hazardous materials table, which must be used on shipping papers and package markings. Using a brand name or common nickname instead is not acceptable.

Related: Basic Description, Shipping Paper, Hazardous Materials Table
Packing Group

A roman numeral I, II, or III assigned to a material to show its degree of danger within a hazard class, with I being the greatest hazard. It influences packaging, quantity limits, and some loading rules.

Related: Basic Description, Hazard Class, Hazardous Materials Table
Hazardous Materials Table

The regulatory listing that gives each hazardous material its proper shipping name, hazard class, UN number, packing group, label codes, and special provisions. It is the reference behind shipping paper entries and package markings.

Related: Proper Shipping Name, Packing Group, Special Provision
Special Provision

A coded instruction in the hazardous materials table that changes or adds to the normal requirements for a specific material. Provisions may affect packaging, quantity limits, communication rules, or loading and segregation.

Related: Hazardous Materials Table, Packing Group, Segregation
Emergency Response Information

Written guidance carried with hazardous materials shipments that tells responders what to do for spills, fires, and exposures. It must accompany the shipping paper and include first aid, firefighting, and spill handling directions.

Related: Shipping Paper, Emergency Response Guidebook, Reportable Quantity
Emergency Response Guidebook

A reference organized by guide number that gives initial isolation distances, protective actions, and firefighting advice for hazardous materials incidents. Responders use the UN number or placard to find the right guide page.

Related: Emergency Response Information, UN Identification Number, Placard
Reportable Quantity

The amount of a hazardous substance that, if released, must be reported to federal, state, and local authorities. Releases at or above this quantity trigger notification duties for the carrier and shipper.

Related: Hazardous Substance, Emergency Response Information, Incident Reporting
Hazardous Substance

A material listed by the EPA as harmful to the environment when released, in addition to being regulated for transport. Spills of these materials may require environmental notification even when the transport hazard is low.

Related: Reportable Quantity, Hazard Class, Incident Reporting
Hazardous Waste

A material regulated as waste that exhibits hazardous characteristics or appears on EPA waste lists. Transporting it requires a uniform hazardous waste manifest and often additional placarding and recordkeeping.

Related: Hazardous Substance, Shipping Paper, Incident Reporting
Segregation

The rule that certain hazardous materials must be kept apart from each other or from food and animal feed during loading and transport. Separation prevents dangerous reactions or contamination if packages leak.

Related: Special Provision, Loading and Unloading, Hazard Class
Cargo Tank

A bulk packaging permanently attached to a vehicle, such as a tank truck used for fuels or chemicals. Cargo tanks require special markings, placards, and driver inspection before loading and after unloading.

Related: Bulk Package, Placard, Loading and Unloading
Loading and Unloading

The procedures for placing and removing hazardous materials cargo, including checking placards, securing packages, and watching for leaks. Drivers must follow shipper instructions and never smoke or use open flames nearby.

Related: Segregation, Cargo Tank, Placard
Incident Reporting

The duty to notify authorities after certain hazmat events, such as a release of a reportable quantity, a fire, or an injury requiring hospitalization. Reports go to the National Response Center and usually state and local agencies.

Related: Reportable Quantity, Hazardous Waste, Emergency Response Information
Security Threat Assessment

The TSA background check required before a hazmat endorsement is issued or renewed. It reviews criminal, immigration, and terrorist-watch records and must be completed before the state can add the endorsement.

Related: Hazardous Materials Endorsement (H), Security Plan, Fingerprint-Based Check
Fingerprint-Based Check

The fingerprint submission that starts the TSA security threat assessment for hazmat applicants. Drivers usually enroll at an approved collection site and pay a fee before the endorsement process can continue.

Related: Security Threat Assessment, Hazardous Materials Endorsement (H), Security Plan
Security Plan

A written plan required for carriers of certain high-risk hazardous materials that covers personnel security, facility access, and en route security. Drivers must follow its procedures and report suspicious activity or security breaches.

Related: Security Threat Assessment, Highway Route Controlled Quantity, Incident Reporting
Highway Route Controlled Quantity

A very large quantity of certain radioactive materials that triggers special routing, security, and notification requirements. Carriers must follow designated routes and meet extra planning and communication duties.

Related: Security Plan, Radioactive Material, Routing
Radioactive Material

Class 7 material that emits ionizing radiation above regulatory limits, shipped under strict packaging, labeling, and dose-rate rules. Drivers should limit time near packages and maximize distance from them.

Related: Highway Route Controlled Quantity, Placard, Hazard Class
Corrosive Material

Class 8 material that destroys skin or metal on contact, including many acids and bases. It can cause severe burns and may react with other cargo, water, or the tank itself.

Related: Hazard Class, Segregation, Personal Protective Equipment
Oxidizer

A Division 5.1 material that supplies oxygen and can make a fire burn faster or hotter, sometimes igniting on contact with fuel. It must be kept away from combustible materials and heat sources.

Related: Organic Peroxide, Hazard Class, Segregation
Organic Peroxide

A Division 5.2 material that can decompose rapidly and violently, especially when heated or contaminated. Some require temperature control, and carriers must watch for heat buildup or damaged packaging.

Related: Oxidizer, Hazard Class, Segregation
Flash Point

The lowest temperature at which a liquid gives off enough vapor to ignite when exposed to a flame. It determines whether a liquid is flammable and how it must be packaged, marked, and placarded.

Related: Flammable Liquid, Division, Hazard Class
Flammable Liquid

A Class 3 liquid with a flash point at or below 140 degrees Fahrenheit, such as gasoline or many solvents. Vapors can travel to an ignition source, so grounding, bonding, and no-smoking rules apply.

Related: Flash Point, Cargo Tank, Loading and Unloading
Personal Protective Equipment

Gloves, eye protection, boots, aprons, or respirators worn to reduce exposure while handling hazardous materials. The shipping paper and emergency information indicate the protection needed for a specific product.

Related: Corrosive Material, Emergency Response Information, Loading and Unloading
Routing

The selection of roads a hazmat vehicle may use, which can be restricted by tunnels, bridges, cities, or designated hazmat routes. Drivers must plan ahead because some routes are prohibited for certain classes or quantities.

Related: Highway Route Controlled Quantity, Security Plan, Segregation