Pennsylvania CDL HazMat study materials
Pennsylvania CDL HazMat study resources

Pennsylvania CDL HazMat key terms

Pennsylvania CDL HazMat · Get comfortable with the vocabulary.

Hazardous Material

Any substance or material capable of posing an unreasonable risk to health, safety, or property when transported in commerce, as listed in the Hazardous Materials Table or meeting a defined hazard class.

Related: Hazardous Materials Table, Hazard Class
Hazardous Materials Table

The regulatory listing in 49 CFR 172.101 that names each regulated material and specifies its hazard class, identification number, packing group, required labels, and packaging exceptions.

Related: Basic Description, Packing Group
Hazard Class

One of nine categories defining the type of danger a material presents, such as explosives, flammable liquids, oxidizers, toxic substances, or radioactive material, each with its own rules.

Related: Division, Hazardous Material
Division

A subdivision within a hazard class that narrows the hazard, such as Class 1 explosives split into divisions 1.1 through 1.6 or Class 2 gases split into 2.1, 2.2, and 2.3.

Related: Hazard Class, Compatibility Group
Packing Group

A rating of I, II, or III assigned to a material showing its degree of danger, where I is great danger, II is moderate danger, and III is minor danger.

Related: Hazardous Materials Table, Performance-Oriented Packaging
Basic Description

The required sequence on a shipping paper giving the identification number, proper shipping name, hazard class or division, and packing group, in that order, for each hazardous material.

Related: Proper Shipping Name, Identification Number
Proper Shipping Name

The name of a hazardous material exactly as it appears in the Hazardous Materials Table, which must be used on shipping papers and package markings instead of a brand or common name.

Related: Basic Description, Hazardous Materials Table
Identification Number

A four-digit number, sometimes preceded by UN or NA, that identifies a hazardous material and appears on shipping papers, package markings, and orange placards.

Related: Placard, Basic Description
Emergency Response Information

Written guidance that must accompany hazardous materials shipping papers, describing immediate hazards, firefighting and spill response, and first aid so responders can act before arriving.

Related: Emergency Response Guidebook, Shipping Paper
Shipping Paper

The transport document, such as a bill of lading or manifest, that describes hazardous materials in the required basic description and must be kept within reach of the driver while driving.

Related: Basic Description, Emergency Response Information
Emergency Response Guidebook

A reference book, commonly called the ERG, that organizes hazardous materials by guide number and gives initial isolation distances, protective actions, and first aid for responders.

Related: Emergency Response Information, Isolation Distance
Placard

A diamond-shaped warning sign, at least 10.75 inches square, attached to a vehicle or bulk package to show the hazard class of the contents being transported.

Related: Identification Number, Placard Table
Placard Table

The chart in 49 CFR 172.504 that specifies which hazard classes and quantities require placards on a vehicle, including the 1,001-pound aggregate rule for Table 2 materials.

Related: Placard, Aggregate Gross Weight
Aggregate Gross Weight

The combined weight of all hazardous materials in a vehicle that fall under Placard Table 2, used to decide when the 1,001-pound placarding threshold is reached.

Related: Placard Table, Placard
Label

A smaller diamond-shaped warning sticker, about 4 inches on each side, placed on a non-bulk package to show the hazard class of the material inside it.

Related: Placard, Non-Bulk Packaging
Marking

Required information printed or attached directly on a package, such as the proper shipping name, identification number, orientation arrows, or the word OVERPACK, that communicates contents and handling needs.

Related: Proper Shipping Name, Overpack
Overpack

An enclosure such as a box or crate used to consolidate one or more packages for handling, which must itself be marked with the word OVERPACK and the required markings of the inner packages.

Related: Marking, Non-Bulk Packaging
Non-Bulk Packaging

A package with a capacity of 119 gallons or less for liquids, or a net mass of 882 pounds or less for solids, that generally requires labels rather than placards.

Related: Bulk Packaging, Label
Bulk Packaging

A package with a capacity greater than 119 gallons for liquids, more than 882 pounds net mass for solids, or more than 1,000 pounds water capacity for gases.

Related: Non-Bulk Packaging, Cargo Tank
Cargo Tank

A tank permanently attached to a motor vehicle, or forming part of the vehicle frame, used to carry liquid or gaseous hazardous materials in bulk.

Related: Portable Tank, Bulk Packaging
Portable Tank

A bulk container that is not permanently attached to a vehicle, is designed to be lifted on and off, and must meet specific design and test requirements for the materials it carries.

Related: Cargo Tank, Bulk Packaging
Segregation

The required separation of incompatible hazardous materials, or of hazardous materials from food and animal feed, during loading and transport to prevent dangerous reactions or contamination.

Related: Compatibility Group, Securement
Securement

The use of tiedowns, blocking, bracing, or shoring to keep packages and containers from shifting, sliding, or falling during transport, as required for all cargo including hazardous materials.

Related: Segregation, Bulk Packaging
Compatibility Group

A letter designation A through S, excluding I, that groups explosives by chemical similarity so that only compatible groups may be loaded together without special approval.

Related: Division, Segregation
Poison Inhalation Hazard

A material, often a gas or volatile liquid, that is toxic when inhaled and requires special handling, inhalation hazard markings, and specific loading and parking precautions.

Related: Hazard Zone, Isolation Distance
Hazard Zone

A letter A through D assigned to poison inhalation hazards indicating the severity of the inhalation risk, with Zone A being the most dangerous and requiring the strictest controls.

Related: Poison Inhalation Hazard, Isolation Distance
Isolation Distance

The radius, given in the Emergency Response Guidebook, within which people should be kept away from a spill or fire involving a hazardous material during the initial response.

Related: Emergency Response Guidebook, Poison Inhalation Hazard
Radioactive Material

Material that spontaneously emits ionizing radiation above defined limits, requiring special shipping papers, labels, placards, and secure loading rules, including exclusive-use shipment options.

Related: Exclusive Use, Yellow-III Label
Exclusive Use

A shipment arrangement where a single shipper uses an entire vehicle or container, allowing certain relaxed rules but requiring the vehicle to be dedicated to that load until delivery.

Related: Radioactive Material, Securement
Hazardous Waste

A material that is discarded or intended to be discarded and meets hazardous waste criteria, requiring a uniform hazardous waste manifest and specific shipping paper notations.

Related: Uniform Hazardous Waste Manifest, Shipping Paper
Uniform Hazardous Waste Manifest

A multi-copy tracking form that follows a hazardous waste shipment from generator through transporter to the disposal facility, documenting each handoff and final receipt.

Related: Hazardous Waste, Shipping Paper
Reportable Quantity

The amount of a hazardous substance released that triggers immediate notification to the National Response Center, typically one pound unless the material has a different listed quantity.

Related: National Response Center, Incident Reporting
National Response Center

The federal clearinghouse that must be notified immediately, by telephone, when a hazardous material release meets or exceeds a reportable quantity during transportation.

Related: Reportable Quantity, Incident Reporting
Incident Reporting

The written report required after certain hazardous materials events, such as a release, fire, or injury, submitted to the responsible federal agency within the specified time after the event.

Related: Reportable Quantity, National Response Center
Performance-Oriented Packaging

Packaging that must pass standardized tests, such as drop, stacking, and pressure tests, for the packing group and material it will hold, rather than meeting a prescribed design.

Related: Packing Group, Non-Bulk Packaging
Attended Vehicle

A parked hazardous materials vehicle that remains within the driver's view and control, a requirement for parking certain loads unless the vehicle is properly secured and unattended rules apply.

Related: Parking Rules, Poison Inhalation Hazard
Parking Rules

Restrictions on where a hazardous materials vehicle may be left, including distance from bridges, tunnels, buildings, and places of public assembly, and when the engine may be left running.

Related: Attended Vehicle, Poison Inhalation Hazard
Smoking and Open Flame

A prohibition on smoking or carrying open flames near vehicles carrying flammable, oxidizing, or explosive materials, including during loading, unloading, and while parked.

Related: Parking Rules, Segregation