CHMSP study materials
CHMSP study resources

CHMSP key terms

CHMSP · Get comfortable with the vocabulary.

CERCLA

A federal law that funds and directs cleanup of releases of hazardous substances and assigns liability to potentially responsible parties. It also created the Superfund program and requires reporting of certain releases.

Related: Reportable Quantity (RQ), Cradle-to-Grave Liability, Corrective Action
RCRA

A federal statute governing generation, transport, treatment, storage, and disposal of solid and hazardous waste. It establishes the cradle-to-grave framework, generator categories, and minimum technical standards for facilities.

Related: Characteristic Hazardous Waste, Hazardous Waste Manifest, Large Quantity Generator (LQG)
EPCRA

A federal law requiring facilities to report hazardous chemical inventories and releases to emergency planners and the public. It supports community right-to-know and local emergency planning committees.

Related: Reportable Quantity (RQ), Safety Data Sheet (SDS), Emergency Response Guidebook (ERG)
Hazardous Waste Manifest

A shipping document that accompanies hazardous waste from its point of generation to an off-site receiving facility. It tracks custody, supports cradle-to-grave accountability, and must be signed by each handler.

Related: Cradle-to-Grave Liability, RCRA, Large Quantity Generator (LQG)
Reportable Quantity (RQ)

The threshold amount of a hazardous substance that, when released within 24 hours, triggers federal notification requirements. RQs are substance-specific and appear in regulations and shipping papers.

Related: CERCLA, EPCRA, Safety Data Sheet (SDS)
Safety Data Sheet (SDS)

A standardized document providing hazard, handling, and emergency information for a chemical product. It contains sixteen sections covering identification, composition, first aid, firefighting, accidental release, storage, and disposal.

Related: Permissible Exposure Limit (PEL), Personal Protective Equipment (PPE), Reportable Quantity (RQ)
Cradle-to-Grave Liability

The principle that hazardous waste generators remain responsible for their waste from creation through final disposal, even after it leaves their site. It drives careful selection of transporters and disposal facilities.

Related: Hazardous Waste Manifest, CERCLA, RCRA
Characteristic Hazardous Waste

Waste that exhibits at least one regulated property: ignitability, corrosivity, reactivity, or toxicity. It is identified by testing or by knowledge of the waste and is regulated even without being specifically listed.

Related: RCRA, Flash Point, LD50
Large Quantity Generator (LQG)

A hazardous waste generator that produces at least 1,000 kilograms per month or more than 1 kilogram per month of acutely hazardous waste. LQGs face stricter accumulation, training, and reporting requirements.

Related: RCRA, Hazardous Waste Manifest, Characteristic Hazardous Waste
SPCC Plan

A site-specific plan required for facilities that store certain quantities of oil, designed to prevent discharges to navigable waters. It includes containment, inspection, training, and response procedures.

Related: Process Safety Management (PSM), Emergency Response Guidebook (ERG)
Process Safety Management (PSM)

An OSHA rule requiring employers to manage highly hazardous chemicals through process hazard analysis, operating procedures, training, mechanical integrity, and emergency planning. It aims to prevent catastrophic releases.

Related: Safety Data Sheet (SDS), Incident Command System (ICS), Medical Surveillance
LD50

The dose of a substance that kills half of a test population under defined conditions, usually expressed as milligrams per kilogram of body weight. Lower values indicate greater acute toxicity.

Related: LC50, Dose-Response Relationship, Characteristic Hazardous Waste
LC50

The concentration of a substance in air or water that kills half of a test population during a specified exposure period. It is used to compare acute inhalation or aquatic toxicity.

Related: LD50, Dose-Response Relationship, Vapor Pressure
Bioaccumulation

The net buildup of a substance in an organism from all exposure routes, including food, water, and air. It reflects uptake and elimination rates and can lead to body burdens above environmental concentrations.

Related: Biomagnification, Octanol-Water Partition Coefficient (Kow), Exposure Pathway
Biomagnification

The increase in concentration of a persistent substance at successively higher levels of a food chain. It occurs when organisms retain contaminants faster than they excrete or metabolize them.

Related: Bioaccumulation, Octanol-Water Partition Coefficient (Kow), Exposure Pathway
Octanol-Water Partition Coefficient (Kow)

A ratio of a chemical's concentration in octanol to its concentration in water at equilibrium. Higher values indicate greater lipid solubility and tendency to bioaccumulate.

Related: Bioaccumulation, Biomagnification, Vapor Pressure
Flash Point

The lowest temperature at which a liquid gives off enough vapor to form an ignitable mixture with air near its surface. It is used to classify flammable and combustible liquids.

Related: Vapor Pressure, Characteristic Hazardous Waste, Incineration
Vapor Pressure

The pressure exerted by a substance's vapor when it is in equilibrium with its liquid or solid at a given temperature. Higher values indicate greater volatility and potential for inhalation exposure.

Related: Flash Point, LC50, Exposure Pathway
Dose-Response Relationship

The observed relationship between the amount of a substance administered or absorbed and the intensity of the resulting biological effect. It is fundamental to toxicity assessment and risk characterization.

Related: LD50, LC50, Exposure Pathway
Exposure Pathway

The route by which a person or ecological receptor comes into contact with a contaminant, including source, medium, exposure point, and route of entry. It is used in risk assessment to link contamination to receptors.

Related: Bioaccumulation, Dose-Response Relationship, Personal Protective Equipment (PPE)
Permissible Exposure Limit (PEL)

An occupational exposure limit set by OSHA as the maximum permissible airborne concentration of a substance over a typical work shift. It is enforceable and may be adjusted for extended shifts.

Related: STEL, IDLH, Medical Surveillance
Immediately Dangerous to Life or Health (IDLH)

A concentration of an airborne contaminant that poses an immediate threat to life, would cause irreversible health effects, or would impair escape. It guides respirator selection and emergency response decisions.

Related: Permissible Exposure Limit (PEL), Emergency Response Guidebook (ERG), Hot Zone
Short-Term Exposure Limit (STEL)

An occupational exposure limit for a short-term exposure, typically fifteen minutes, that should not be exceeded at any time during the workday. It protects against acute effects from brief high concentrations.

Related: Permissible Exposure Limit (PEL), IDLH, Vapor Pressure
Personal Protective Equipment (PPE)

Equipment worn or used by workers to protect against chemical, physical, or biological hazards. Examples include gloves, goggles, aprons, and respirators, selected based on hazard assessment.

Related: Respirator Fit Test, Decontamination, Permissible Exposure Limit (PEL)
Respirator Fit Test

A procedure that checks whether a respirator seals properly against the user's face. Qualitative tests detect leakage by taste or smell; quantitative tests measure leakage numerically.

Related: Personal Protective Equipment (PPE), IDLH, Confined Space
Confined Space

An enclosed or partially enclosed space with limited entry and exit, not designed for continuous occupancy, and potentially hazardous due to atmosphere, engulfment, or configuration. Entry requires evaluation and controls.

Related: IDLH, Respirator Fit Test, Medical Surveillance
Medical Surveillance

A program of periodic health evaluations for workers exposed to specific hazards, intended to detect adverse effects early. It may include history, physical exams, and biological monitoring.

Related: Permissible Exposure Limit (PEL), Personal Protective Equipment (PPE), Confined Space
Incident Command System (ICS)

A standardized, scalable command structure used to manage emergency response operations. It defines roles, span of control, and common terminology to coordinate multiple agencies and resources.

Related: Unified Command, NIMS, Hot Zone
National Incident Management System (NIMS)

A national framework that provides common standards for incident management across agencies and jurisdictions. It integrates command, resource management, communications, and preparedness activities.

Related: Incident Command System (ICS), Unified Command, Emergency Response Guidebook (ERG)
Emergency Response Guidebook (ERG)

A reference book used by first responders to identify initial isolation and protective action distances for hazardous materials incidents. It organizes materials by UN number and guide number.

Related: Reportable Quantity (RQ), Hot Zone, Incident Command System (ICS)
Hot Zone

The area immediately surrounding a hazardous materials release where contamination or serious harm is possible. Only trained personnel in appropriate protective equipment may enter.

Related: Decontamination, IDLH, Incident Command System (ICS)
Decontamination

The process of removing or neutralizing contaminants from people, equipment, or surfaces to prevent spread and exposure. It is typically conducted between the hot and cold zones.

Related: Hot Zone, Personal Protective Equipment (PPE), Unified Command
Unified Command

An incident management arrangement in which multiple agencies with jurisdictional or functional responsibility jointly set objectives and direct response operations. It preserves individual authority while ensuring coordinated action.

Related: Incident Command System (ICS), NIMS, Decontamination
Secure Landfill

An engineered disposal facility with liners, leachate collection, and cover systems designed to contain hazardous waste and limit releases. It requires monitoring and long-term care after closure.

Related: Corrective Action, Solidification/Stabilization, Incineration
Incineration

A thermal treatment process that destroys hazardous organic constituents by high-temperature combustion. It reduces volume and toxicity but requires air pollution controls and ash management.

Related: Secure Landfill, Solidification/Stabilization, Flash Point
Solidification/Stabilization

A treatment that mixes waste with binders to reduce mobility of contaminants or improve physical handling. Solidification encapsulates waste; stabilization chemically immobilizes contaminants.

Related: Secure Landfill, Incineration, Corrective Action
Bioremediation

A treatment that uses microorganisms to degrade or transform contaminants in soil, groundwater, or waste. It may be enhanced by adding nutrients, oxygen, or specialized cultures.

Related: Pump-and-Treat, Soil Vapor Extraction (SVE), Corrective Action
Pump-and-Treat

A remediation method that extracts contaminated groundwater, treats it above ground, and often reinjects or discharges the cleaned water. It controls plumes but may require long operating periods.

Related: Bioremediation, Soil Vapor Extraction (SVE), Corrective Action
Soil Vapor Extraction (SVE)

A remediation technique that applies vacuum to soil to draw volatile contaminants into extraction wells for above-ground treatment. It works best in permeable, unsaturated soils with volatile compounds.

Related: Vapor Pressure, Pump-and-Treat, Bioremediation
Corrective Action

The regulatory process for investigating and cleaning up releases at hazardous waste treatment, storage, and disposal facilities. It addresses soil, groundwater, and other media under a facility-wide approach.

Related: RCRA, Secure Landfill, Pump-and-Treat