Textile Printing and Finishing Related to Dyed Goods
Printing is localised dyeing, so the same dye chemistry applies but the dye is delivered in a paste and fixed afterwards. Finishing alters appearance, handle or performance and can shift the shade of already-dyed goods - a frequent exam theme.
Printing methods and fixation
- Block, flat-screen, rotary-screen, roller, transfer and digital inkjet are the main routes; screens give repeat accuracy and productivity.
- Print paste contains dye or pigment, thickener (sodium alginate for reactive, guar gum, emulsion thickener for pigment), and auxiliaries such as urea, alkali or acid, and a reducing or oxidising agent as needed.
- Fixation: steaming for reactive and acid dyes, thermosol dry heat at 180–210 °C for disperse dyes, curing at about 150 °C for pigment prints with binder.
- After-treatment: washing-off of thickener and unfixed dye for dye prints; no washing for pigment prints.
Finishing that touches colour
- Mercerisation with strong caustic under tension increases lustre, strength and dye uptake - the same recipe then gives a deeper shade on mercerised cotton.
- Calendering, raising, sanforising change surface and therefore apparent colour and lustre.
- Chemical finishing - softening, resin crease-resist, water repellent, flame retardant - may yellow whites, affect fastness or require curing that alters shade.
- Stenter drying and heat-setting must be controlled to avoid shade variation across the width.
Worked example
A cotton voile is dyed to a standard navy, then mercerised. The shade comes out deeper and brighter. Reasoning: mercerisation swells the fibre, increases accessible amorphous area and dye uptake. Remedy: either mercerise the fabric before dyeing and dye to the standard, or re-standardise the recipe for pre-mercerised goods. Never compare shades between mercerised and unmercerised substrate.
Traps
- Steaming a pigment print instead of curing the binder.
- Forgetting that thickener must be washed out of dye prints.
- Treating mercerisation as a purely mechanical finish.